Third Quantization for Order Parameter (I): BCS-BEC crossover with macroscopically coherent state
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Quantum Physics arXiv:2604.21288 (quant-ph) [Submitted on 23 Apr 2026] Title:Third Quantization for Order Parameter (I): BCS-BEC crossover with macroscopically coherent state Authors:Guo-Jian Qiao, Miao-Miao Yi, Xin Yue, C. P. Sun View a PDF of the paper titled Third Quantization for Order Parameter (I): BCS-BEC crossover with macroscopically coherent state, by Guo-Jian Qiao and 2 other authors View PDF HTML (experimental) Abstract:We revisit the quantization of the order parameter, which we refer to as third quantization, from the perspective of the commutation relation between the phase operator of the order parameter and the particle-number operator. We show that this macroscopic commutation relation does not constitute an independent fundamental postulate added to quantum mechanics, but instead emerges naturally from second quantization in the thermodynamic limit for both bosonic and fermionic many-body systems. In this sense, both Bose-Einstein condensates (BECs) and Bardeen-Cooper-Schrieffer (BCS) states can be understood as macroscopic quantum states described by bosonic coherent states: in BEC, bosons condense into a single coherent mode with a well-defined phase, while in BCS systems, collective excitations of Cooper pairs can also acquire an effectively bosonic coherent description. On this basis, we propose a new macroscopic interpretation of the BCS-BEC crossover. To characterize this crossover, we model a conventional superconductor as an assembly of macroscopically separated superconducting segments. As the intra-segment coupling increases, the system evolves from a BCS-like regime toward a BEC-like regime, in which the segments collectively behave as macroscopic coherent states. Inter-segment tunneling then locks their phases, establishes global phase coherence, and gives rise to a bulk Bose-Einstein condensate. The phase diagram of the BCS-BEC crossover can thus be understood as a manifestation of a macroscopic quantum process governed by the coherent-state dynamics of the order parameter. Our results provide a unified perspective on BEC, BCS superconductivity, and the BCS-BEC crossover within the framework of third quantization. Comments: Subjects: Quantum Physics (quant-ph) Cite as: arXiv:2604.21288 [quant-ph] (or arXiv:2604.21288v1 [quant-ph] for this version) https://doi.org/10.48550/arXiv.2604.21288 Focus to learn more arXiv-issued DOI via DataCite (pending registration) Submission history From: Guo-Jian Qiao [view email] [v1] Thu, 23 Apr 2026 05:05:30 UTC (308 KB) Full-text links: Access Paper: View a PDF of the paper titled Third Quantization for Order Parameter (I): BCS-BEC crossover with macroscopically coherent state, by Guo-Jian Qiao and 2 other authorsView PDFHTML (experimental)TeX Source view license Current browse context: quant-ph new | recent | 2026-04 References & Citations INSPIRE HEP NASA ADSGoogle Scholar Semantic Scholar export BibTeX citation Loading... BibTeX formatted citation × loading... Data provided by: Bookmark Bibliographic Tools Bibliographic and Citation Tools Bibliographic Explorer Toggle Bibliographic Explorer (What is the Explorer?) Connected Papers Toggle Connected Papers (What is Connected Papers?) Litmaps Toggle Litmaps (What is Litmaps?) scite.ai Toggle scite Smart Citations (What are Smart Citations?) Code, Data, Media Code, Data and Media Associated with this Article alphaXiv Toggle alphaXiv (What is alphaXiv?) Links to Code Toggle CatalyzeX Code Finder for Papers (What is CatalyzeX?) DagsHub Toggle DagsHub (What is DagsHub?) GotitPub Toggle Gotit.pub (What is GotitPub?) Huggingface Toggle Hugging Face (What is Huggingface?) ScienceCast Toggle ScienceCast (What is ScienceCast?) Demos Demos Replicate Toggle Replicate (What is Replicate?) Spaces Toggle Hugging Face Spaces (What is Spaces?) Spaces Toggle TXYZ.AI (What is TXYZ.AI?) Related Papers Recommenders and Search Tools Link to Influence Flower Influence Flower (What are Influence Flowers?) Core recommender toggle CORE Recommender (What is CORE?) Author Venue Institution Topic About arXivLabs arXivLabs: experimental projects with community collaborators arXivLabs is a framework that allows collaborators to develop and share new arXiv features directly on our website. Both individuals and organizations that work with arXivLabs have embraced and accepted our values of openness, community, excellence, and user data privacy. arXiv is committed to these values and only works with partners that adhere to them. Have an idea for a project that will add value for arXiv's community? Learn more about arXivLabs. Which authors of this paper are endorsers? | Disable MathJax (What is MathJax?)