A Surface-Scaffolded Molecular Qubit

Quantum Physics arXiv:2601.19976 (quant-ph) [Submitted on 27 Jan 2026] Title:A Surface-Scaffolded Molecular Qubit Authors:Tian-Xing Zheng, M.

Iqbal Bakti Utama, Xingyu Gao, Moumita Kar, Xiaofei Yu, Sungsu Kang, Hanyan Cai, Tengyang Ruan, David Ovetsky, Uri Zvi, Guanming Lao, Yu-Xin Wang, Omri Raz, Sanskriti Chitransh, Grant T. Smith, Leah R. Weiss, Magdalena H. Czyz, Shengsong Yang, Alex J. Fairhall, Kenji Watanabe, Takashi Taniguchi, David D. Awschalom, A. Paul Alivisatos, Randall H. Goldsmith, George C. Schatz, Mark C. Hersam, Peter C. Maurer View a PDF of the paper titled A Surface-Scaffolded Molecular Qubit, by Tian-Xing Zheng and 25 other authors View PDF HTML (experimental) Abstract:Fluorescent spin qubits are central building blocks of quantum technologies. Placing these qubits at surfaces maximizes coupling to nearby spins and fields, enabling nanoscale sensing and facilitating integration with photonic and superconducting devices. However, reducing the dimensions or size of established qubit systems without sacrificing the qubit performance or degrading the coherence lifetime remains challenging. Here, we introduce a surface molecular qubit formed by pentacene molecules scaffolded on a two-dimensional (2D) material, hexagonal boron nitride (hBN). The qubit exhibits stable fluorescence and optically detected magnetic resonance (ODMR) from cryogenic to ambient conditions. With fully deuterated pentacene, the Hahn-echo coherence reaches 22 $\mu$s and further extends to 214 $\mu$s under dynamical decoupling, outperforming state-of-the-art shallow NV centers in diamond, despite being positioned directly on the surface. We map the local spin environment, resolving couplings to nearby nuclear and electron spins that can serve as auxiliary quantum resources. This platform combines true surface integration, long qubit coherence, and scalable fabrication, opening routes to quantum sensing, quantum simulation, and hybrid quantum devices. It also paves the way for a broader family of 2D material-supported molecular qubits. Comments: Subjects: Quantum Physics (quant-ph); Mesoscale and Nanoscale Physics (cond-mat.mes-hall); Materials Science (cond-mat.mtrl-sci) Cite as: arXiv:2601.19976 [quant-ph] (or arXiv:2601.19976v1 [quant-ph] for this version) https://doi.org/10.48550/arXiv.2601.19976 Focus to learn more arXiv-issued DOI via DataCite (pending registration) Submission history From: Tian-Xing Zheng [view email] [v1] Tue, 27 Jan 2026 19:00:00 UTC (5,223 KB) Full-text links: Access Paper: View a PDF of the paper titled A Surface-Scaffolded Molecular Qubit, by Tian-Xing Zheng and 25 other authorsView PDFHTML (experimental)TeX Source view license Current browse context: quant-ph new | recent | 2026-01 Change to browse by: cond-mat cond-mat.mes-hall cond-mat.mtrl-sci References & Citations INSPIRE HEP NASA ADSGoogle Scholar Semantic Scholar export BibTeX citation Loading... BibTeX formatted citation × loading... Data provided by: Bookmark Bibliographic Tools Bibliographic and Citation Tools Bibliographic Explorer Toggle Bibliographic Explorer (What is the Explorer?) Connected Papers Toggle Connected Papers (What is Connected Papers?) Litmaps Toggle Litmaps (What is Litmaps?) scite.ai Toggle scite Smart Citations (What are Smart Citations?) Code, Data, Media Code, Data and Media Associated with this Article alphaXiv Toggle alphaXiv (What is alphaXiv?) Links to Code Toggle CatalyzeX Code Finder for Papers (What is CatalyzeX?) DagsHub Toggle DagsHub (What is DagsHub?) GotitPub Toggle Gotit.pub (What is GotitPub?) Huggingface Toggle Hugging Face (What is Huggingface?) Links to Code Toggle Papers with Code (What is Papers with Code?) ScienceCast Toggle ScienceCast (What is ScienceCast?) Demos Demos Replicate Toggle Replicate (What is Replicate?) Spaces Toggle Hugging Face Spaces (What is Spaces?) Spaces Toggle TXYZ.AI (What is TXYZ.AI?) Related Papers Recommenders and Search Tools Link to Influence Flower Influence Flower (What are Influence Flowers?) Core recommender toggle CORE Recommender (What is CORE?) Author Venue Institution Topic About arXivLabs arXivLabs: experimental projects with community collaborators arXivLabs is a framework that allows collaborators to develop and share new arXiv features directly on our website. Both individuals and organizations that work with arXivLabs have embraced and accepted our values of openness, community, excellence, and user data privacy. arXiv is committed to these values and only works with partners that adhere to them. Have an idea for a project that will add value for arXiv's community? Learn more about arXivLabs. Which authors of this paper are endorsers? | Disable MathJax (What is MathJax?)